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Surfactant-free CO2-based microemulsion-like systems

Surfactant-free CO2-based microemulsion-like systems

                                                         Robert F. Hankel, Paula E. Rojas, Mary Cano-Sarabia, Santi Sala, Jaume Veciana, Andreas Braeuer* and Nora Ventosa* Chem. Commun., 2014,50, 8215-8218

Grafting of Metallacarboranes onto Self-Assembled Monolayers Deposited on Silicon Wafers

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Dr. Emilio José Juárez-Pérez, Dr. Michel Granier, Prof. Clara Viñas, Dr. P. Hubert Mutin, Dr. Rosario Núñez,*; Chemistry – An Asian Journal Volume 7, Issue 2, pages 277–281, February 6, 2012

DOI: 10.1002/asia.201100750


Stuck on you: Amine-, oxyamine-, and isocyanate-terminated self-assembled monolayers were deposited on silicon wafers for reaction with cobaltabisdicarbollide derivatives. The reaction of the isocyanate group with [NMe4][8-NH2-C4H8O2-3,3-Co(1,2-C2B9H10)(1,2-C2B9H11)] gave homogeneous monolayers of cobaltabisdicarbollide moieties covalently linked to the surface (see picture).

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