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Reversible Control of Crystalline Rotors by Squeezing Their Hydrogen Bond Cloud Across a Halogen Bond-Mediated Phase Transition

Reversible Control of Crystalline Rotors by Squeezing Their Hydrogen Bond Cloud Across a Halogen Bond-Mediated Phase Transition

Cyprien Lemouchi, Hiroshi M. Yamamoto, Reizo Kato, Sergey Simonov, Leokadiya Zorina,Antonio Rodríguez-Fortea, Enric Canadell, Pawel Wzietek, Konstantinos Iliopoulos, Denis Gindre, Michael Chrysos, and Patrick Batail*.      Cryst. Growth Des., 2014, 14 (7), pp 3375–3383

Grafting of Metallacarboranes onto Self-Assembled Monolayers Deposited on Silicon Wafers

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Dr. Emilio José Juárez-Pérez, Dr. Michel Granier, Prof. Clara Viñas, Dr. P. Hubert Mutin, Dr. Rosario Núñez,*; Chemistry – An Asian Journal Volume 7, Issue 2, pages 277–281, February 6, 2012

DOI: 10.1002/asia.201100750


Stuck on you: Amine-, oxyamine-, and isocyanate-terminated self-assembled monolayers were deposited on silicon wafers for reaction with cobaltabisdicarbollide derivatives. The reaction of the isocyanate group with [NMe4][8-NH2-C4H8O2-3,3-Co(1,2-C2B9H10)(1,2-C2B9H11)] gave homogeneous monolayers of cobaltabisdicarbollide moieties covalently linked to the surface (see picture).

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