SCIENTIFIC HIGHLIGHTS

03 June 2015

DOI: 10.1021/acs.inorgchem.5b00618DOI: 10.1021/acs.inorgchem.5b00618

A set of different generations of porphyrin-cored poly(aryl ether) dendrimers decorated with 4, 8, 16, or 32closo-carborane clusters are obtained by controlled regioselective hydrosilylation in high yield. Dendrimers are fully characterized by IR-FTR, NMR, and elemental analysis; additionally, the hydrodynamic radius (RH) for some dendrimers has been estimated from diffusion coefficients determined by DOSY NMR experiments. The photoluminescence properties of these dendrimers are not largely affected by the functionalization with carboranes.

 

 

 

 

 

Hits: 6510
Bioactive materials for therapy and diagnosis

High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties




INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA, Copyright © 2020 ICMAB-CSIC | Privacy Policy | This email address is being protected from spambots. You need JavaScript enabled to view it.