Tris-pyridylmethylamine (TPMA) complexes functionalized with persistent nitronyl nitroxide organic radicals
- Autores: Elena Badetti,* Vega Lloveras, Francesca Anna Scaramuzzo, Klaus Wurst, Jaume Veciana, José Vidal-Gancedo,* Giulia Licini and Cristiano Zonta *
Dalton Trans., 2020,49, 10011-10016
- Mentions: Tris-pyridylmethylamine (TPMA) complexes functionalized with persistent nitronyl nitroxide organic radicals
The chance to have persistent organic radicals in combination with metals has attracted much interest since it offers the possibility of having new functional molecules with multiple open-shell elements. In this study, we report the synthesis of two tripodal tris(2-pyridyl)methylamine ligands (TPMA) functionalized with nitronyl nitroxide persistent radicals. The newly formed ligands have been used to coordinate zinc(II), copper(II), iron(II) and cobalt(II).
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