Laura León-Reina, Aurelio Cabeza, Jordi Rius, Pedro Maireles-Torres, Ana C. Alba-Rubio, Manuel López Granados;
Journal of Catalysis, Volume 300, April 2013, Pages 30–36
Calcium diglyceroxide has been reported as a very active phase in the transesterification of triglycerides with methanol for biodiesel production. This work reports on the determination of the crystal structure of Ca diglyceroxide by Patterson-based direct methods from synchrotron X-ray powder diffraction (XRD) data in combination with characterisation by Differential Thermal Analysis-Thermogravimetry (DTA-TG), Scanning Electron Microscopy (SEM) and X-ray Photoelectron and Fourier Transform-Infrared spectroscopies (XPS and FT-IR). Its crystal structure is formed by molecular tetramers held together by a complex H-bond network. Both the XRD structural determination and the O1s XPS core level indicate the presence of a basic non-protonated O− anion at the surface of Ca diglyceroxide. Along with the presence of surface lipophilic CHxunits, this O− anion may be the origin of this molecule’s high activity relative to CaO.
Two relevant surface features of Calcium diglyceroxide have been disclosed by surface characterisation and determination of its crystal structure: the presence of basic unsaturated O anion and the presence of lipophilic CHx units. Both characteristics can favour two key steps of the reaction mechanism: methoxide formation and nucleophilic attack of the latter to the carbonyl groups of triglyceride molecule.