We have investigated the radical functionalization of gold surfaces with a derivative of the perchlorotriphenylmethyl (PTM) radical using two methods: by chemisorption from the radical solution and by on-surface chemical derivation from a precursor.
We have investigated the obtained self-assembled monolayers by photon-energy dependent X-ray photoelectron spectroscopy. Our results show that the molecules were successfully anchored on the surfaces. We have used a robust method that can be applied to a variety of materials to assess the stability of the functionalized interface. The monolayers are characterized by air and X-ray beam stability unprecedented for films of organic radicals. Over very long X-ray beam exposure we observed a dynamic nature of the radical–Au complex. The results clearly indicate that (mono)layers of PTM radical derivatives have the necessary stability to withstand device applications.
Tuneable and low cost molecular electronics
Stability of radical-functionalized gold surfaces by self-assembly and on-surface chemistry
Tobias Junghoefer, Ewa Malgorzata Nowik-Boltyk, J. Alejandro de Sousa, Erika Giangrisostomi, Ruslan Ovsyannikov, Thomas Chassé, Jaume Veciana, Marta Mas-Torrent, Concepció Rovira, Núria Crivillers and Maria Benedetta Casu *
Chem. Sci., 2020,11, 9162-9172