ICMAB Research
A new paper has been published in the journal Acta Cryst. B Structural Science, Crystal Engineering and Materials:
The presence of magnetic atoms at the A and B sites and the coupling between these two spin subsystems in perovskites gives rise to a variety of exciting effects. In particular this coupling attracts interest from the field of novel multiferroic and magnetoelectric oxides. Moreover, magnetic double perovskites presenting cationic order at the B sites incorporate an additional modulation that can favor symmetry breaking, multiferroic, magnetoelectric and polar phases.
Here, we describe the magnetic structures obtained from neutron diffraction and analyze the symmetry properties of well ordered A2MnB′O6 double perovskites with A = Lu, Yb, Tm, Er, Ho, Y, Tb, La0.5Tb0.5, La and B′ = Co or Ni. A rich variety of magnetic orders is formed that have been identified and described, and their symmetry properties are discussed in relation to the multiferroic and magnetoelectric properties of the different compounds.
A new paper has been published in the journal Acta Cryst. B Structural Science, Crystal Engineering and Materials:
The presence of magnetic atoms at the A and B sites and the coupling between these two spin subsystems in perovskites gives rise to a variety of exciting effects. In particular this coupling attracts interest from the field of novel multiferroic and magnetoelectric oxides. Moreover, magnetic double perovskites presenting cationic order at the B sites incorporate an additional modulation that can favor symmetry breaking, multiferroic, magnetoelectric and polar phases.
Here, we describe the magnetic structures obtained from neutron diffraction and analyze the symmetry properties of well ordered A2MnB′O6 double perovskites with A = Lu, Yb, Tm, Er, Ho, Y, Tb, La0.5Tb0.5, La and B′ = Co or Ni. A rich variety of magnetic orders is formed that have been identified and described, and their symmetry properties are discussed in relation to the multiferroic and magnetoelectric properties of the different compounds.
M4ELC Sustainable Electronics
Symmetry, magnetic transitions and multiferroic properties of B-site-ordered A2MnB′O6 perovskites (B′ = [Co, Ni])
Jose Luis Garcia-Muñoz, Xiaodong Zhang, Gloria Subías & Javier Blasco
Acta Cryst. B Structural Science, Crystal Engineering and Materials, Volume 80, Part 6, December 2024, Pages 665-675
DOI: 10.1107/S2052520624009454


![Symmetry, magnetic transitions and multiferroic properties of B-site-ordered A2MnB′O6 perovskites (B′ = [Co, Ni])](/templates/yootheme/cache/f4/26_03_2025_web-f4ba60d0.jpeg)